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BP网络拟合电位滴定曲线用其一次微商确定滴定终点

Artificial Neural Networks and the First Derivative Method Applied to Potentiometric Titration1

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【作者】 高志明李井会朱秀慧陈瑾赵春玲

【Author】 GAO Zhi Ming LI Jing Hui * ZHU Xiu Hui CHEN Jin ZHAO Chun Ling (Department of Applied Chemistry, Anshan Institute of Iron & Steel Technology, Anshan\ 114002)

【机构】 鞍山钢铁学院应用化学系!鞍山114002

【摘要】 使用改进的BP算法 ,避免了可能产生的麻痹现象 ,对几处酸及烷基磷酸酯及深井水样的电位滴定曲线进行拟合 ,用少量的实验数据恢复了大量的体系信息 ,并用曲线一次微商极大值确定电位滴定终点。

【Abstract】 A three\|layer artificial neural network is used to fit the curve of the potentiolmetric titration. The paralysis in the procedure of training of ANN has been avoided with the improved delta(δ) of output layer.A great amount of information of the system is obtained from a small number of experimental data point,The end\|points determined by the first derivative of those data picked from the fitted curves of the titration of Chloride acid,Acetic acid, Phosphorous acid and Dodecyl phosphate, underground water with Sodium hydroxide are accurate.

  • 【文献出处】 计算机与应用化学 ,COMPUTERS AND APPLIED CHEMISTRY , 编辑部邮箱 ,2000年Z1期
  • 【分类号】O655-39
  • 【被引频次】5
  • 【下载频次】78
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