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Ni-Cr-Al-Y涂层真空热处理过程中元素的行为

EVOLUTION OF ELEMENT DISTRIBUTION IN Ni-Cr-Al-Y COATING BEFORE AND AFTER VACUUM HEAT TREATMENT

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【作者】 王冰黄荣芳宫骏王启民梁越孙超闻立时韩雅芳

【Author】 WANG Bing; HUANG Rongfang; GONG Jun; WANG Qimin; LIANG Yue; SUN Chao; WEN Lishi (Institute of Metal Research, The Chinese Academy of Sciences, Shenyang 110015) HAN Yafang (Beijing institute of Aeronautical Materials, Beijing 100095)

【机构】 中国科学院金属研究所!沈阳110015北京航空材料研究院!北京100095

【摘要】 采用电弧离子镀技术在铸造镍基合金 K17和 Ni3Al基合金 IC-6上沉积 Ni-Cr-Al-Y涂层结果表明,在沉积过程中由于电弧离子镀的“溅射”和“反溅射”效应以及基体和涂层发生互扩散的共同作用下,沉积的 Ni-Cr-Al-Y涂层在靠近基体区含有少量基体元素,如 Co, Ti和 Mo等 K17合金中的 Al元素可抑制 Cr由涂层向基体扩散 IC-6合金中由于还含有 Mo元素,使这种抑制作用进一步增强在 1050 ℃真空热处理时,各元素互扩散能力增强,大量的 Cr克服 Al和 Mo元素的束缚向基体扩散,最终使两种合金上沉积的Ni-Cr-Al-Y涂层中的元素均匀分布。

【Abstract】 Ni-based alloy K17 and Ni3Al-based alloy IC-6 were used as substrates coated with Ni-Cr-Al-Y coating deposited by arc ion plating (AIP). The results of the tests show that a few of elements of Co, Ti and Mo etc., which come from substrates were observed in near-surface zones of NiCr-Al-Y coating. It corresponds to the "sputter" and "anti-sputter" effect of AIP during deposition process. Atoms Cr distributed from coating to substrate were inhibited by Al contained in alloy K17. In alloy IC-6 with high concentration of Mo, the’ restraint becomes stronger. During vacuum heat treatment at IO50 ℃, the activities of various elements were increased, while the resistance of diffusion of Cr by Al and Mo was decreased. A great deal of Cr diffuses from coating to substrate. As a result, the distributions of various elements are not only homogeneity but also close to nominal compositions.

【基金】 .NULL.
  • 【文献出处】 金属学报 ,ACTA METALLRUGICA SINICA , 编辑部邮箱 ,2000年10期
  • 【分类号】TG15
  • 【被引频次】17
  • 【下载频次】195
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