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新型金属团簇化合物光限幅特性实验研究

Study on the optical limiting properties of the novel pentanuclear ‘open’ planar shaped metal cluster compound

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【作者】 杨昆曲士良张驰赵秀丽方光宇宋瑛林忻新泉

【Author】 Yang Kun,Qu Shiliang,Zhang Chi ,Zhao Xiuli,Fang Guanyu Song Yinglin,Xin Xinquan  (Department of Applied Physics,Harbin Institute of Technology,Harbin,150001) ( ?State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institut

【机构】 哈尔滨工业大学应用物理系!哈尔滨150001南京大学配位化学国家重点实验室!南京210093南京大学配位化学?

【摘要】 研究了平面开式五核金属团簇化合物 [WOS4 Cu4 I2 (py) 6 ]对 532nm激光的光限幅特性 ,并与同等条件下的富勒烯比较 ,其光限幅特性优于富勒烯。利用Z scan技术研究表明 ,该团簇化合物光限幅的主要非线性光学机制为激发态吸收。

【Abstract】 The optical limiting properties of the novel pentanuclear ‘open’ planar shaped metal cluster compound WOS 4Cu 4I 2(py) 6 for 532nm laser pulse was studied. The optical limiting performance is better than that of fullerene under the same condition. The results measured with Z scan technique show that the excited state absorption is the main mechanism of the optical limiting in the metal cluster solution.

  • 【分类号】TN24
  • 【被引频次】6
  • 【下载频次】111
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