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A facile route for the syntheses of trisilanes containing C-mono-substituted carborane

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【作者】 骆玉美刘菲吴世晖

【Author】 LUO,Yu-Mei LIU,Fei WU,Shi-HuiDepartment of Chemistry,Fudan University,Shanghai 200433 , China

【机构】 Department of ChemistryFudan UniversityShanghai 200433ChinaChina

【摘要】 <正> The syntheses of trislanes containing C-monosubstituted o-carborane are described.Hie intermediate compound,2-chloro-2-phenyl-hexamethyltrisilane,was prepared by elimination reaction between 2,2-diphenylhexamethyltrisilane and hydrogen chloride with a catalytic amount of aluminum chloride in chloroform solution.

【Abstract】 The syntheses of trislanes containing C-monosubstituted o-carborane are described.Hie intermediate compound,2-chloro-2-phenyl-hexamethyltrisilane,was prepared by elimination reaction between 2,2-diphenylhexamethyltrisilane and hydrogen chloride with a catalytic amount of aluminum chloride in chloroform solution.

【关键词】 Synthesistrisilanecarborane
【Key words】 Synthesistrisilanecarborane
【基金】 Project (No. 29272040) supported by the National Natural Science Foundation of China
  • 【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2000年06期
  • 【分类号】O627.4
  • 【下载频次】4
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