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Syntheses and molecular self-assembly of chiral phosphorami-dates

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【作者】 杜大明； 花文廷； 王建武； 金祥林；

【Author】 DU,Da-Ming HUA,Wen-Ting WANG,Jian-WuJIN,Xiang-LinCollege of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China College of Chemistry,Shandong University,Jinan,Shandong 250100,China

【机构】 College of Chemistry and Molecular Engineering； Peking University； Beijing 100871； China； College of Chemistry； Shandong University； Jinan； Shandong 250100； China； China；

【摘要】 <正> Two chiral phosphoramidates,(R)-(-)-1,1’-binaphthyl-2,2’-dihydroxy-N-[α-(S)-methylbenzyl] phosphoramidate and (-)-1,1’-biphenyl-2,2’-dihydroxy-N-[α-(S)-methylbenzyl]-phosphoramidate were synthesized.Their crystal structures were determined by X-ray single crystal diffraction analysis.The phosphoramidate molecules are self-associated by inter-molecular N-H...O = P hydrogen bonds and aromatic edge to face interactions.

【Abstract】 Two chiral phosphoramidates,(R)-(-)-1,1’-binaphthyl-2,2’-dihydroxy-N-[α-(S)-methylbenzyl] phosphoramidate and (-)-1,1’-biphenyl-2,2’-dihydroxy-N-[α-(S)-methylbenzyl]-phosphoramidate were synthesized.Their crystal structures were determined by X-ray single crystal diffraction analysis.The phosphoramidate molecules are self-associated by inter-molecular N-H...O = P hydrogen bonds and aromatic edge to face interactions.

【关键词】 Phosphoramidate； hydrogen bond； crystal structure；
【Key words】 Phosphoramidate； hydrogen bond； crystal structure；
【基金】 Project supported by the National Natural Science Foundation of China (Grant No. 29872023);the Ministry of Education of China (Research Funds for Chinese Scholars returning from abroad);China Postdoctoral Science Foundation
  • 【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2000年05期
  • 【分类号】O621
  • 【下载频次】1
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