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Resistance of the anodic PbO film formed in sulfuric acid solution

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【作者】 柳厚田梁海河杨炯周伟舫

【Author】 LIU, Hou-Tian LIANG, Hai-He YANG, JiongZHOU, Wei-FangDepartment of Chemistry, Fudan University, Shanghai 200433, China

【机构】 Department of ChemistryFudan UniversityShanghai 200433ChinaChina

【摘要】 <正> The resistance of the anodic PbO film fonned on lead at 0.9 V (vs. Hg/Hg2SO4) in 4.5 mol/dm3 H2SO4 was measured using alternating-current impedance method. The resistance of the anodic PbO film was found to be close to that of the interstitial liquid among the PbO particles in the film, suggesting that the interstitial liquid may serve as the major passage for ion transportation during the film growth.

【Abstract】 The resistance of the anodic PbO film fonned on lead at 0.9 V (vs. Hg/Hg2SO4) in 4.5 mol/dm3 H2SO4 was measured using alternating-current impedance method. The resistance of the anodic PbO film was found to be close to that of the interstitial liquid among the PbO particles in the film, suggesting that the interstitial liquid may serve as the major passage for ion transportation during the film growth.

【基金】 Project supported by the National Natural Science Foundation of China (No. 29873013).
  • 【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2000年04期
  • 【分类号】O614
  • 【被引频次】1
  • 【下载频次】5
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