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磺化聚醚酮酮热分解动力学研究

STUDY ON THE KINETICS OF THERMAL DEGRADATION OF THE SULPHONATED POLYETHERKETONEKETONE

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【作者】 易回阳曾繁涤

【Author】 YI Hui yang 1,ZENG Fan di 2 (1.Department of Chemistry,Hubei Normal University,Huangshi 435002,China;2.Department of Chemistry,Huazhong University of Science and Technology,Wuhan 430074,China)

【机构】 湖北师范学院化学系!湖北黄石435002华中理工大学化学系!湖北武汉430074

【Abstract】 The process of thermal degradation of sulphonated polyetherketoneketone (SPEKK) was studied by the thermogravimetry (TG) and differential thermal gravinetric analysis (DTG).There were two weight loss steps in TG for SPEKK.The first one was the -SO 3H aparts from the main chain of SPEKK,the activation energy was found to be 67.44kJ/mol.The second,was the polymer main chain degradated of which the activation energy was about 210.4kJ/mol.The thermal degradation of SPEKK was in agreement with the models of random initation.

【基金】 湖北省教委科研资助项目
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2000年04期
  • 【分类号】O631.31
  • 【被引频次】2
  • 【下载频次】91
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