【摘要】 通过手性二茂铁亚胺环钯化合物（Sp,Sp）-[{Pd[（η⁵-C₅H₅）Fe1{（η⁵-C₅H₃）C（CH3）=N-Ar}]（μ-Cl）}₂],手性二茂铁亚胺环汞化合物[HgCl{η⁵-C₅H₅)Fe（η⁵-C₅H₃）C（CH3）=N-Ar}]与金属锡的金属转移反应,均得到保持茂环平面手性的手性二茂铁亚胺环锡化合物.产物均经元素分析、IR和¹H NMR鉴定,X射线晶体结构分析确定了有机锡化合物的绝对构型,并经CD谱验证.更多还原

【Abstract】 A series of optically active cyclostannated ferrocenylimines were synthesized by transmetallation of optically active cyclopalladated and cyclomercurated ferrocenylimines with metallic tin, respectively. All of the yielded compounds were characterized by elemental analysis, IR and 1H NMR. The crystal structures and absolute configurations of the complex were determined by X - ray diffraction and checked by CD spectra.更多还原