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全氟或多氟烷基氯代烷在保险粉引发下与芳香烃的反应
Sodium Dithionite - induced Reaction of Per (poly)fluoroalkyl Chlorides with Aromatic Compounds
【摘要】 全氟或多氟烷基氯代烷在保险粉引发下在DMSO溶剂中可以与富电子芳香烃反应,方便地得到氟烷基化的产物.氟烷基化产物的结构和产率主要取决于取代基的供电子能力和位置.
【Abstract】 Per (poly) fluoroalkyl chlorides could smoothly react with electron - rich aromatic compounds induced by sodium dithionite in DMSO to give the per ( poly) fluoroalkylated aromatics. The structures and yields of perfiuoroalkylated products depend mainly on the positions and electron - donating ability of the substituents.
【基金】 国家自然科学基金(29772048)资助
- 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2000年06期
- 【分类号】O621.25
- 【被引频次】5
- 【下载频次】151