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CO~+彗尾带系(A~2Π-X~2∑~+)(2,3)带速度调制激光光谱研究

Study on the Rotational Spectra of the Weak Band (2, 3) in the Comet-tail System (A~2Π-X~2∑~+) of CO~+ Using Velocity-Modulation Laser Spectroscopy

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【作者】 杨晓华陈扬骎蔡佩佩王荣军卢晶晶

【Author】 Yang Xiaohua; Chen Yangqin; Cai Peipei, Wang Rongjun; Lu Jingjing (Department of Physics East China Normal University, Laboratory for Quantum Optics, East China Normal University, Shanghai 200062)

【机构】 华东师范大学物理系国家教育部华东师范大学量子光学开放实验室!上海200062华东师范大学物理系国家教育部华东师范大学量

【摘要】 利用差分速度调制分子离子激光光谱技术,首次测量了 CO彗尾带系(AΠ-X)(2,3)弱带转动吸收光谱,通过对测量谱线的标识,获得了两态的分子常数,其中下态v=3的常数未见有文献报导。在锁相放大器1s积分时间下,实验系统的吸收测量灵敏度实测为 1.56 x 10-6

【Abstract】 Using differential velocity-modulation spectroscopic technique, the Doppler-limited rotational absorption spectra of the weak band (2, 3) in the Comet-tail system (A2Π-X2+) of CO+ were measured. The assignment was made for all the observed spectra. Furthermore the effective molecular constants of the states involved in the transition were obtained, and the constants of the lower state v" =3 were reported for first time as to our knowledge. The absorption sensitivity of the experimental sytem was measured to be 1.56 x 10-6 under the 1 s lock -in amplifier integration time.

【关键词】 速度调制CO+分子常数
【Key words】 Velocity-modulationCO~+Molecular constant
【基金】 国家自然科学基金!(批准号:19974011);波谱与原子分子物理国家重点实验室!(批准号:991516)资助课题。
  • 【文献出处】 化学物理学报 ,CHINESE JOURNAL OF CHEMICAL PHYSICS , 编辑部邮箱 ,2000年04期
  • 【分类号】O561
  • 【被引频次】9
  • 【下载频次】38
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