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液态低沸点气体的表面张力
The Surface Tension of Liquid Gases for Low-boiling Point
【摘要】 利用双毛细管法测定了液氮沸点温度下液氮的表面张力.用非线性方程γ=γ0(1-T/TC)n描述了液态N2、O2、Ar、Xe、H2、Ne、He、F2和Kr的表面张力与温度的关系,并采用一元线性回归的方法拟合了上述各流体的多数γ0和n,准确度高于文献值,说明方程能正确表达表面张力与温度的关系.这些数据有利于对上述低沸点气体进行准确的热力学计算.
【Abstract】 The surface tension of liquid nitrogen at 77K is measured to be 9.053dyn/cm in terms of the double capillary method, which may be reasonable in comparison with the single capillary method. The nonlinear equation γ=γ°(1 - T/TC)n has been used to describe the relation between the surface tension with the temperature for liquefied N2, O2, Ar, Xe, H2, Ne, He, F2,D2 and Kr. The parameters γ0 and n of the liquefied gases above are fitted by the linear regression method with higher accuracy than that in the literatures.
【关键词】 表面张力;
低沸点气体;
双毛细管法;
【Key words】 Surface tension; Low-boiling point gas; Double capillary method;
【Key words】 Surface tension; Low-boiling point gas; Double capillary method;
【基金】 国防科技重点实验室基金!98JS77.7.JW1903
- 【文献出处】 化学物理学报 ,CHINESE JOURNAL OF CHEMICAL PHYSICS , 编辑部邮箱 ,2000年03期
- 【分类号】O647
- 【被引频次】8
- 【下载频次】384