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RTM专用双马来酰亚胺树脂体系流变特性及模拟分析研究

RHEOLOGICAL BEHAVIOR CHARACTERIZATION AND MODELING OF THE 4503A BISMALEIMIDE RESIN FOR RTM PROCESSING

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【作者】 林云段跃新梁志勇邓燕平张明习

【Author】 LIN Yun 1, DUAN Yue xin 1, LIANG Zhi yong 1, DENG Yan ping 2, ZHANG Ming xi 2 (1. Faculty 104, Beijing University of Aeronautics and Astronautics, Beijing 100083, China) (2. The 3 rd Laboratory, 637 Research Institute, Jinan 250023, China)

【机构】 北京航空航天大学104教研室!北京100083济南637研究所3室!山东济南250023

【摘要】 研究了 RTM专用双马来酰亚胺树脂体系的流变特性 ,并根据树脂不同温度下反应机理的不同 ,建立其分段粘度模型 ,粘度模拟结果与实验结果具有良好的一致性。所建立的粘度模型 ,可有效预测和模拟该树脂体系在不同工艺条件下的粘度行为 ,揭示了树脂体系的优化工艺参数和低粘度平台工艺窗口 ,为合理拟订RTM工艺参数和保证产品质量提供了必要的科学依据

【Abstract】 The rheological behaviors of bismaleimide resin (4503A) for resin transfer molding (RTM) are studied with DSC and viscosity experiments. A viscosity model is established and used to simulate rheological behaviors of the resin. It is shown that subsection viscosity models should be employed to describe the viscosity characteristics of the resin because of the different curing mechanisms of the resin at different temperatures. The estimated viscosity of the models is in good agreement with that of the experiments. The low viscosity plaque and a processing window of the resin are determined based on the developed models. The optimum processing parameter of the 4503A resin for RTM is 80℃ at which the viscosity of the resin will be less than 300cP within 71 minutes. The developed viscosity models will be important for processing simulation and quality control for high performance composites of RTM processing.

【关键词】 复合材料RTM工艺树脂粘度模拟
【Key words】 compositesRTMresinviscositysimulation
【基金】 国家自然科学基金 !( N o.5 9773 0 0 4);航空科学基金!( 97G5 10 64 )
  • 【文献出处】 航空学报 ,ACTA AERONAUTICA ET ASTRONAUTICA SINICA , 编辑部邮箱 ,2000年S1期
  • 【分类号】V258
  • 【被引频次】13
  • 【下载频次】250
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