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发泡铜阴极电沉积法回收酸性镀铜废液中的铜

Electrodeposition Using Foamed Copper as Cathodes for Recovering Copper from Copper Electroplating Acidic Waste Solution

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【作者】 李保山牛玉舒全明秀胡壮麒翟玉春

【Author】 LI Bao-shan1,2, NIU Yu-shu2, QUAN Ming-xiu1, HU Zhuang-qi1, ZHAI Yu-chun3 (1. SKLRSNA Inst. Metal., CAS, Liaoning Shenyang 110015, China; 2. Fushun Petroleum Inst., Liaoning Fushun 113001, China; 3. Northeastern Univ. Material and Metall. College, Li

【机构】 中国科学院金属研究所快速凝固非平衡合金国家重点实验室!辽宁 沈阳 110015抚顺石油学院辽宁 抚顺113001中国科学院金属研究所快速凝固非平衡合金国家重点实验室!辽宁 沈阳 110015中国科学院金属研?

【摘要】 用发泡铜作阴极材料, 从稀的酸性镀铜废液中电沉积回收金属铜,测定了阴极极化曲线,考察了pH值、电解液循环速率、电流密度等工艺参数对阴极电流效率的影响. 结果表明:用发泡铜作阴极材料,可有效地处理含铜废液和回收金属铜,将含Cu2+ 200 mg/L的废液在1.2 A/dm2表观电流密度下处理至含Cu2+ 0.5 mg/L以下,平均电流效率可达85%以上.

【Abstract】 Electrodeposition using foamed copper as cathode for recovering copper from copper electroplating acidic dilute waste solution was studied. The polarization curve of the electrodeposition system was measured and the influences of pH value, flow rate of electrolyte, current density and other factors on current efficiency were investigated. The results show that it is very effective for recovering copper in waste water using foamed copper as cathode. Under the apparent current density of 1.2 A/dm2, the waste water with 200 mg/L Cu2+ was treated and the copper content reduced to below 0.5 mg/L, the average current efficiency is higher than 85%. The X-ray diffraction spectrum of the cathode after electrodeposition shows that it is covered by pure copper.

【关键词】 发泡铜电极电沉积废液处理
【Key words】 foamed metalelectrodeselectrodepositionwaste water treatmentcopper
【基金】 国家自然科学基金!(编号:59871014);中国石油化工集团基金!(编号:199110)
  • 【文献出处】 化工冶金 ,ENGINEERING CHEMISTRY & METALLURGY , 编辑部邮箱 ,2000年04期
  • 【分类号】TF111.52
  • 【被引频次】1
  • 【下载频次】169
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