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混煤燃烧过程中矿物质的形态变化及相变

CONFORMATION CHANGE AND PHASE TRANSFORMATION OF MINERALS DURING COAL BLENDS COMBUSTION

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【作者】 王泉海邱建荣李帆刘迎晖郑楚光

【Author】 Wang Quanhai ** , Qiu Jianrong,Liu Yinghui and Zheng Chuguang (National Laboratory of Coal Combustion,Huazhong University of Science and Technology,Wuhan 430074,China)

【机构】 华中理工大学煤燃烧国家重点实验室!武汉430074

【Abstract】 In this paper,the ash fusion characteristics and mineral behavior of individual coal ash and a series of two-component blendsd ashes are studied.The samples are heated progressively from(IT)at 100?℃intervals in reducing atmosphere.Mineral composition and type at each temperature interval are determined by X-ray diffraction (XRD)analysis.For different coal ashes,the main mineral matter at 800?℃is quartz,anhydrite and hematite,calcite and feldspar.With increasing temperature,oxidation,thermal decomposition,transformation and reaction occur between the components.It can be seen that quartz,anhydrite decrease and anorthite,gehlenite increase.At about 1200?℃,all of mineral diminish and a glass phase is formed.Some combinations of mineral in component coal produce low-melting eutectic composition at a high temperature and this is the main reason causing the non-arithmetic average of softening temperature of blends ash.

【基金】 国家自然科学基金!资助项目 (No.5 9876 0 12 )
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2000年06期
  • 【分类号】TQ534
  • 【被引频次】28
  • 【下载频次】253
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