【摘要】 以 1 2 -钼磷酸和三乙醇胺为原料合成了一种新型电荷转移盐 [C6H10 O3 N]3 PMo12 O4 0 ·2H2 O .用C、H、N元素分析 ,ICP ,TG -DTA ,X射线衍射 ,IR、UV光谱对该化合物进行了表征 .结果表明 :1 2 -钼磷酸与三乙醇胺形成电荷转移盐后 ,其阴离子的Keggin结构基本不变 ,但其特征振动峰的位置发生了一定的位移 .还对该电荷转移盐的氧化还原性质及导电性等进行了讨论 .更多还原

【Abstract】 The charge-transfer salt [C 6H 10 O 3N] 3PMo 12 O 40 ·2H 2O was synthesized in aqueous solution from 12_molybdophosphate acid and triethanolamine. It was characterized by elemental analysis, ICP, IR and UV spectra. The results indicate that the structure of anion has a little change after the charge-transfer salt formed, but the characteristic vibrational bands have some shifts. Also studied its spectrum,oxidation-reduction property and solid electrical conductivity.更多还原