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溴醇法合成环氧苯乙烷的研究
Synthesis of Styrene Oxide Via Styrene Bromohydrin
【摘要】 研究了溴醇法合成环氧苯乙烷原料配比和添加催化剂对收率的影响 ,当NaBr的添加量为化学反应计量时 ,在添加催化剂和最佳反应条件下 ,收率可达 80 .6% (含量 97.5 % )。将NaBr溶液回收套用 3次 ,当苯乙烯加料量为 1mol时 ,获得环氧苯乙烷平均收率为 72 .5 % (含量 92 .7% ) ,NaBr平均消耗量为 0 .4 6mol。
【Abstract】 The effect of feed ratio and catalysts on the yield of styrene oxide has been investigated. The yield of 80.6%(content 97.5%) of styrene oxide was obtained under the optimum conditions. When the recovered NaBr solution was reused three times, for 1mol styrene the average yield of styrene oxide and NaBr consumption were 72.5%(content 92.7% of styrene oxide) and 0.46 mol, respectively.
- 【文献出处】 合成化学 ,CHINESE JOURNAL OF SYNTHETIC CHEMISTRY , 编辑部邮箱 ,2000年01期
- 【分类号】TQ241
- 【被引频次】48
- 【下载频次】310