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电导法研究树脂与游离酸的相互作用

Interaction Between Resin and Free Acid by Electric Conductance Method

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【作者】 陈任宏陈炳稔袁萍陈秀芳

【Author】 Chen Renhong, Chen Bingren *, Yuan Ping, Chen Xiufang (Guangdong Medical Secondary High School,Guangzhou 510520,China) (*Department of Chemistry,South China Normal University,Guangzhou 510631,China)

【机构】 广东省医药学校!广州510520华南师范大学化学系!广州510631

【摘要】 利用电导实验技术跟踪树脂吸附游离酸的行为 ,讨论了外加盐和乙醇等因素对吸附的影响 ,利用固 -液相互作用方程求取吸附剂 -吸附质相互作用能。实验结果表明 ,树脂吸附游离酸 ,其表观吸附速率常数随着外加盐离子浓度的增大而减少 ;表观吸附速率常数与吸附剂 -吸附质相互作用能存在线性关系。

【Abstract】 The adsorption of low concentration of free acid by resin was followed by electric conductance method.The effect of the ionic concentration of added salt on adsorption was discussed.The interaction energy between the adsorbent and the adsorbate was obtained by the interaction equation of the solid-liquid.The experimental results show that the apparent adsorption rate decrease with the increase in the ionic concentration of added salt.There was a linear interactionship between the adsorption apparent rate constant and adsorbent-adsorbate interaction energy.

  • 【文献出处】 广州化学 ,GUANGZHOU CHEMISTRY , 编辑部邮箱 ,2000年02期
  • 【分类号】O647
  • 【被引频次】1
  • 【下载频次】38
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