【摘要】 合成了一种新的含未配位氮和氧两种不同配位能力原子的高分子顺二羰基铑 (I)配合物—聚 2-乙烯吡啶 -顺丁烯二酸甲酯 /铑 (即 PVMRh) ,用 X射线光电子能谱 (XPS)和红外光谱 (IR)进行了跟踪分析 ,确定了 PVMRh存在的配位结构特征 ,发现这种结构特征和配合物的稳定性有密切关系 ;并在可比条件下 ,以甲醇羰基化实验对这一新配合物与现有工业催化剂的催化性能进行了比较 .更多还原

【Abstract】 A new kind of polymer cis-carbonyl Rhodium complex, which contained two kinds of atoms with different coordinated power, has been synthesized. After study on its data of IR and XPS following the tracks of its structural change, the feature of intramolecular substitution reaction is found and it has great effect on the stability of polymer rhodium complex. Its catalytic properties are examined by parallel experiments in comparable conditions.更多还原