【摘要】 合成了四 (对羟基苯基 )卟啉镍与 meso-四 (2 -羧甲氧基苯基 )卟啉镍 ,并用循环伏安法研究了两种金属卟啉的电化学性质 ,得到了一些有意义的结果更多还原

【Abstract】 Tetra(4 hydroxyphenyl) porphrin was synthesized by condensation of 4 hydroxybenzaldehyde and pyrrole in DMF using anhydrous AlCl 3 as catalyst without necessity to us inert gas for protection. Its nickel complex and Ni meso tetra[2 (carboxymethylenoxy)phenyl] porphyrin were also prepared. The electrochmeical property of TCMOPPNi was also prepared. The electrochemical property of TCMPOPPNi has been investigated in DMSO by cyclic voltammetry and differential pulse voltammetry.更多还原