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[PMo9V3O40]6-硫代物的合成及光谱研究
Synthesis and Spectroscopic Studies of the Oxothio Heteropolyanio n of [PMo9V3O40]6-
【摘要】 通过H2 S与杂多化合物 (NH4 ) 4H2 [PM9V3 O4 0 ]·10H2 O在DMF中反应合成了其硫代产物 ,并对其进行了红外和拉曼光谱表征
【Abstract】 Some compounds were obtained through addition H 2S to the heteropoly-compound (NH 4) 4H 2[PMo 9V 3O 40]·10H 2 O in dimethyformamide.The FTIR spectrum and NIR FT-Raman spectrum of these comp ounds were investigated.The spectroscopic studies of the compound Ⅱshowed that it is a oxothio heteropoly-compound.
【关键词】 杂多阴离子;
FTIR光谱;
NIR FT-Raman光谱;
【Key words】 Heteropolyanion; FTIR spectra; NIR FT-Raman s pectra;
【Key words】 Heteropolyanion; FTIR spectra; NIR FT-Raman s pectra;
【基金】 结构化学国家重点实验室(990 0 2 1 )资助
- 【文献出处】 光谱学与光谱分析 ,SPECTROSCOPY AND SPECTRAL ANALYSIS , 编辑部邮箱 ,2000年05期
- 【分类号】O614
- 【被引频次】1
- 【下载频次】41