节点文献
连苯三酚氧化产物及其金属配合物的合成及表征
Synthesis and Characterization of the Oxidation Product of the 1,2,3-trihydroxybenzene and Its Metalic Complexes
【摘要】 在abinitio量子化学研究的基础上 ,研究了连苯三酚的氧化反应 ,并合成了连苯三酚氧化产物与水合肼的缩合物及其金属配合物 ,用IR、Raman光谱和热重分析 ,确定了配合物的组成及THBO的可能结构。
【Abstract】 The oxidation reaction mechanism of the 1,2,3 -t rihydroxybenzene was studied by the Ab initio calculation of the quantum chemist ry. The derivative of the hydrazine and THBO(the reaction product of the 1,2,3- trihydroxybenzene and H 2O 2) and its metal complexes were synthesized and cha racterized by the IR,Raman spectrum and thermogravimetric analysis. The composit ion of these complexes and the possible structure of THBO were confirmed.
【关键词】 连苯三酚;
水合肼;
金属配合物;
振动光谱;
【Key words】 trihydroxybenzene; Hydrazine; Metal co mplexes; Vibration spectrum.;
【Key words】 trihydroxybenzene; Hydrazine; Metal co mplexes; Vibration spectrum.;
【基金】 结构化学国家重点实验室资助;福建省自然科学基金资助
- 【文献出处】 光谱学与光谱分析 ,SPECTROSCOPY AND SPECTRAL ANALYSIS , 编辑部邮箱 ,2000年05期
- 【分类号】O627
- 【被引频次】5
- 【下载频次】182