【摘要】 本文用溶解度法研究水溶液中Ir(Ⅳ )与氯离子的配合情况 ,得到在不同温度下的积累稳定常数和在 2 98K时各级配合过程的ΔH°、ΔG°和ΔS°值。更多还原

【Abstract】 The complexing of Ir(Ⅳ)with Cl - ions was studied at ionic strength 3 0 and 293K,298K and 308K by solubility method.The consecutive stability constants at different temperatures and thermodynamic parameters ΔH°,ΔG° and ΔS° during the complexation of Ir(Ⅳ)with Cl - ions were calculated from the experimental date.更多还原