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吐温80-硫酸铵-水的固液体系萃取分离Pt(Ⅳ)、Pd(Ⅱ)、Ir(Ⅳ)碘络阴离子
The Separation of Iodine Complex Anions of Pt,Pd,Ir by Liquid-Solid Extraction System of Tween 80-Salt-Water
【摘要】 报道了吐温 (Tween) 80 - (HN4) 2 SO4-水的固液萃取体系中Pt(Ⅳ )、Pd(Ⅱ)、Ir(Ⅳ )碘络阴离子的萃取行为 ,在HCl-NH4I介质中 ,该体系可萃取Pt(Ⅳ)、Pd(Ⅱ)、Ir(Ⅳ ) ,而贱金属不被萃取 ,可用于Pt、Pd、Ir与贱金属的分离。对合成样进行了萃取分离 ,并初步探讨其机理。
【Abstract】 A new method for the separation of iodine complex anions of Pt,Pd,Ir through liquid-solid extraction system of Tween 80-salt-water was investigated.In the medium of HCl-NH 4I,the proposed method can separate Pt,Pd,Ir and has been used for the separation of Pt,Pd,Ir in the synthetic samples.The mechanism has been studied preliminarily.
- 【文献出处】 贵金属 ,PRECIOUS METALS , 编辑部邮箱 ,2000年03期
- 【分类号】O658
- 【被引频次】17
- 【下载频次】97