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超临界条件下合成晶型骨架的介孔氧化锆

Synthesis of Mesoporous Zirconia with Crystalline Framework in Super-critical Ethanol

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【作者】 赵军平王树国巩雁军吴东孙予罕

【Author】 ZHAO Jun Ping, WANG Shu Guo, GONG Yan Jun, WU Dong, SUN Yu Han * [WT5”BX](State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China) [WT5HZ]

【机构】 中国科学院山西煤炭化学研究所!煤转化国家重点实验室太原030001中国科学院?

【摘要】 采用聚氧乙烯型非离子表面活性剂 ( PEO)为模板剂 ,超临界乙醇为介质 ,在不同条件下 (各种 PEO,不同 p H值和络合剂 )合成了类似于 MSU的介孔氧化锆 .XRD,N2 物理脱吸附曲线 ,TEM及选区电子衍射证明该介孔氧化锆骨架为四方晶型 ;改变表面活性剂类型、络合剂及 p H可调变介孔氧化锆的 BET表面积与孔分布

【Abstract】 By using nonionic polyethylene oxide surface(PEO) as a template, mesoporous zirconia was synthesized in super critical ethanol under different conditions(wide pH, various types of PEO and different chelates). XRD, N 2 adsorption desorption isotherm, TEM and selected area electron diffraction confirmed that the as synthesized powder was mesoporous zirconia with tetragonal walls. Similar to MSU silica, mesoporous zirconia showed single XRD in small angle, spongy like pore arrangement and non monotonic relation between the pore size and the surfactant length. Thus, the analogous assembly mechanism most likely took place for PEO as the template by forming micelles in thermal ethanol. BET surface area and pore size could be modified by varying PEO, pH and chelate. The as synthesized mesoporous zirconia had poor thermal stability. It might be because the calcination caused further crystallization and the deformation of crystalline framework, thus losing the meaoporous structure. It is well known that some oxides such as SiO 2 , Al 2O 3 or TiO 2 can effectively stabilize totragonal zirconia. Therefore, incorporation with SiO 2 , Al 2O 3 or TiO 2 , the meso structure of zirconia successfully retained on the calcination at 673 K, or even up to 723 K in some cases. The related work will be published later. [WT5HZ]

【基金】 国家自然科学基金! (批准号 :2 99710 5 7;2 962 5 3 0 7)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2000年12期
  • 【分类号】O614
  • 【被引频次】32
  • 【下载频次】208
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