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C60-苯乙烯-顺丁烯二酸酐的三元自由基共聚

Free Radical Ternary Copolymerization of C60 with Styrene and Maleic Anhydride

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【作者】 官文超雷洪廖道训

【Author】 GUAN Wen-Chao~1*, LEI Hong~2, LIAO Dao-Xun~2 (1. Department of Chemistry, 2. School of Mechanic Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China)

【机构】 华中理工大学化学系!武汉430074华中理工大学机械科学与工程学院!武汉430074!武汉430074华中理工大学机械科学与工程学院!武汉430074

【Abstract】 A novel C60-styrene-maleic anhydride copolymer was prepared with radical polymerization. 50 mg of C60 and 1 g of styrene and 1 g of maleic anhydride were dissolved in 20 mL of o-dichlorobenzene, then was initiated by 200 mg of BPO at 70 ℃ under the protection of Ar for 32 h. The copolymer was obtained as a brown solid. The structure of copolymer was characterized by UV and FTIR. GPC analyses shows that its average molecular weight Mw is 13 000. The copolymer is soluble in THF, DMSO and water. The surface tension of 0.5% of copolymer aqueous solution was determined to be 54.6×10-3 N/m(20 ℃). TEM analyses shows that the copolymer is a kind of water-soluble nanosphere with the average diameter of about 60 nm.

【基金】 国家自然科学基金!(批准号 :2 9674 0 10 )资助
  • 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,2000年07期
  • 【分类号】O631
  • 【被引频次】10
  • 【下载频次】79
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