节点文献

4-硝基喹啉氧化物激发三重态与甲硫氨酸二肽之间的电子转移

Reaction of Electron Transfer from Methionine-containing Dipeptides to Triplet 4-Nitroquinoline 1-Oxide

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 XU Ye-Ping~*, SONG Qin-Hua, YU Shu-Qin, CHEN Cong-Xiang, MA Xing-Xiao (Department of Chemical Physics, Open Laboratory of Selected-Bond Chemistry of Chinese Academy of Sciences, University of Science and Technology of China, Hefei 230026, China) LIN Wei-Zhen, YAO Si-De (Laboratory of Radiation Chemistry, Shanghai Institute of Nuclear Research, Chinese Academy of Sciences, Shanghai 201800, China)

【机构】中国科学技术大学化学物理系!中国科学院选键化学开放实验室；合肥230026；中国科学院上海原子核研究所辐射化学开放实验室!上海201800；

【Abstract】 Photochemical reactions of 4-nitroquinoline 1-oxide(4NQO) with methionine-containing dipeptides Met-Met, Ala-Met, Met-Lue and Met-Gly have been studies by using 248 nm laser flash photolysis. The formation of α-alkyl radicals was observed, and their rate constants of formation were obtained. The reaction mechanism that the α-alkyl radicals produced via an electron transfer process between triplet 4NQO and methionine-containing dipeptide was proposed.更多还原

【关键词】硝基喹啉氧化物；含甲硫氨酸的肽；激光闪光光解；电子转移；
【Key words】 Nitroquinoline 1-oxide； Methionine-containing dipeptides； Laser flash photolysis； Electron transfer；

【文献出处】高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2000年07期

【分类号】O644
【下载频次】46

知网节下载

节点文献中：

本文链接的文献网络图示:

本文的引文网络

节点文献