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C60接枝聚(N-乙烯基咔唑)的合成、表征及光电导性能

Preparation, Characterization and Photoconductivity of C60 Grafted Poly(N-vinyl carbazole)

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【作者】 李浪陶征洪汪长春杨武利府寿宽

【Author】 LI Lang, TAO Zheng-Hong, WANG Chang-Chun, YANG Wu-Li, FU Shou-Kuan (Department of Macromolecular Science, the Key Laboratory of Molecular Engineering of Polymer of State Education Ministry, Fudan University, Shanghai 200433, China)

【机构】 复旦大学高分子科学系聚合物分子工程教育部重点实验室!上海200433复旦大?

【Abstract】 The C60 grafted poly(N-vinyl carbazole) (PVK) polymer(CGP) was prepared by simple radical polymerization initiated by BPO at 90℃.The products were characterized by UV-Vis, FTIR, GPC and fluorescence and it was proven that C60 was grafted covalently to the PVK. The C60 moiety in the product was about 1. 2% (mass fraction). The photoconductlvity study revealed that the photoconductivity of PVK was improved obviously through grafting C60.The half time of light decaying (t1/2) of CGP reached 0. 35 s.

【基金】 国家自然科学基金;青年基金!(批准号:59703004)
  • 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,2000年05期
  • 【分类号】O631
  • 【被引频次】11
  • 【下载频次】213
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