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1,2,3-三取代贫电子环丙烷衍生物与甲醇反应的研究

Studies on the Reaction of 1,2,3-Trisubstituted Electron-deficient Cyclopropane Derivatives with Methanol

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【作者】 曹卫国丁维钰童玮琦刘欣邱梦遥

【Author】 CAO Wei-Guo, DING Wei-Yu, TONG Wei-Qi, LIU Xin, QIU Meng-Yao ( Department of Chemistry, Shanghai University, Shanghai 201800, China; State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, S

【机构】 上海大学化学系!上海201800中国科学院上海有机化学研究所金属有机化学开放实验室上海200032

【Abstract】 In this paper, the reaction of 1, 2, 3-trisubstituted electron-deficient cyclopropane derivatives ets-1-benzoyl-2-p-substituted phenyl-6, 6-dimethyl-5, 7-dioxo-spiro-[2,5]-4, 8-octadiones with methanol was studied. The structures of the reaction products were confirmed as methyl β-benzoyl-γ-methoxy-γ-p- substituted phenylbutyrates by means of IR, MS, microanalysis, IH, 13C NMR spectroscopies and APT techniques. The reaction mechanism for the formation of the product was also proposed.

【基金】 国家自然科学基金!(批准号:29772021);上海市教育委员会基金;中国科学院上海有机化学研究所金属有机开放实验室基金
  • 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,2000年05期
  • 【分类号】O624
  • 【下载频次】45
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