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2-烷基苯并咪唑在铜表面所成膜热稳定性能的研究
An Investigation of the Thermal Stability of 2-Alkylbenzoimidazole on Copper
【摘要】 分别测定了 2 -烷基苯并咪唑在铜表面所成膜经 1 50 ,2 0 0 ,2 50℃热处理后的 FTIR谱 ,对膜的结构和热稳定性能进行了研究 .结果表明 ,2 -烷基苯并咪唑与铜发生了络合反应 ,并在铜表面形成膜 ,其热稳定性随 2位烷基碳链的增长而减弱 ;由于独特的稠环结构 ,与 2 -烷基咪唑相比 ,热稳定性能增强
【Abstract】 Accumulating on copper surface very guickly in agueous solution, 2 alkylbenzimidazole is an ideal inhibitor and anti corrosion chemical for copper. In this paper, the thermal stability of 2 alkylbenzoimidazoles on copper, which have been treated at 150, 200 and 250 ℃ respectively, has been studied by FTIR. It is indicated that 2 alkylbenzoimidazole on copper has a poor thermal stability as the chain length of alkyl substituent increased, compared with that of 2 alkylimidazoles on copper, the thermal stability of 2 alkylbenzoimidazoles was improved due to their special molecular structure. [WT5HZ]
- 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,2000年04期
- 【分类号】O626
- 【被引频次】7
- 【下载频次】150