【摘要】 报道了 3个取代多联吡啶配体 [4-苯基 -2 ,2′∶ 6′,2″-三联吡啶 ( L1) ,4′,4″-二苯基 -2 ,2′∶ 6′,2″∶ 6″,2 -四联吡啶 ( L2 )和 4′,4 -二苯基 -2 ,2′∶ 6′,2″∶ 6″,2 ∶ 6 ,2″″-五联吡啶 ( L3 ) ]的 4个过渡金属配合物[Co( ) ( L 1) 2 ] ( Cl O4) 2 ( CH3 CN) ( 1) ,[Co( ) ( L 2 ) ( Ac O) ( H2 O) ] ( Cl O4) ( 2 ) ,[Mn( ) ( Ac O) ( L 2 ) ( H2 O) ] .( Cl O4) ( 3 ) ,[Co( ) ( L 3 ) ( CH3 CN) ] ( Cl O4) 2 ( 4 ) ]的合成及其晶体结构 .结构分析表明 ,金属离子对配合物的形成有诱导作用 .更多还原

【Abstract】 The syntheses and crystal structures of transitional metal complexes of three substituted polypyridine ligands[4′-phenyl-2, 2′∶6′, 2″-terpyridine(L1), 4′, 4″-diphenyl-2, 2′∶6′, 2″∶6″, 2-quaterpyridine(L2)and 4′, 4-diphenyl-2, 2′∶6′, 2″∶6″, 2∶6, 2″″-quenquepyridine(L3)] are reported in this work. Comparison of the structures of these complexes shows that the central metal ion has an inducing effect on the formation of the configuration of complexes.更多还原