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氯霉素在Pt/GC离子注入修饰电极上的伏安行为及其测定

Voltammetric Behaviour of Chloramphenicol at Ion Implantation Modified Electrode Pt/GC and Its determination

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【作者】 胡劲波尚军李启隆

【Author】 HU Jing bo,SHANG Jun and LI Qi long  (Department of Chemistry ,Beijing Normal University,Beijing 100875),Fenxi shiyanshi,1999,19(1):27~29

【机构】 北京师范大学化学系!北京100875

【摘要】 氯霉素在浓度为0.1 m ol/L 的NaOH 溶液中,Pt/GC 离子注入修饰电极上有一还原峰,峰电位为 - 0.80 V(vs.SCE),氯霉素的浓度在 1.0×10- 5~1.0×10- 3 m ol/L 范围内与峰电流成正比。检出限为5.0×10- 6 m ol/L。已用于氯霉素眼药水的测定。用线性扫描和循环伏安法研究体系的性质。实验表明,是注入的Pt催化了氯霉素的还原;体系属准可逆过程。

【Abstract】 In 0.1 mol/L NaOH solution,a sensitive reduction peak of chloramphenicol was obtained by linear sweep voltammetry at Pt/GC ion implantation modified electrode.The peak potential is -0.80V( vs .SCE).The linear relationship hold between the peak current and the chloramphenicol concentration ranging from 1.0×10 -5 ~1.0×10 -3 mol/L with a detection limit of 5.0×10 -6 mol/L.The voltammetric behaviour of the system was studied by linear sweep and cyclic voltammetry.Pt is introduced into the GCE surface to catalze the chloramphenicol reduction .The system is quasi reversible.

【基金】 国家自然科学基金!(No.29875003);教育部博士点基金!(No.98102709)
  • 【文献出处】 分析试验室 ,ANALYTICAL LABORATORY , 编辑部邮箱 ,2000年01期
  • 【分类号】O657.1
  • 【被引频次】14
  • 【下载频次】97
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