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蓝色圆珠笔油墨紫外光照射变化的研究

Research About the Variation of Blue Ballpoint Writting Inks Exposured to Ultraviolet Light by Time

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【作者】 王俭孙素琴罗国安张振宇王彦吉冯计民

【Author】 Wang Jian, Sun Suqin, Luo Guoan, Zhang (Department of Chemistry, Tsinghua University, Beijing 100084) Wang Yanji (Department of Forensic Science and Technology, Criminal Police College of China,Shenyang 110035) Feng Jimin (Institute of Forensic Scienc

【机构】 清华大学化学系!北京100084中国刑警学院刑事科学技术系!沈阳110035公安部物证鉴定中心!北京100038

【摘要】 在紫外光照射下,通过对蓝色圆珠笔字迹色痕FT-IR显微光谱的研究,发现溶剂挥 发迅速;其次是环氧树脂的聚合、交联;三苯甲烷染料的分解比较缓慢;而醇酸树脂相对稳定。 该研究为字迹色痕的进一步分辨提供了新方法,同时为字迹色痕的“年龄”推断奠定了基础。 选用相关峰的相对峰高比来描述这一变化,并进行曲线拟合,消除了国笔力不同而引起的油 墨流出量不同造成的误差,这在实际工作中是很有意义的。

【Abstract】 The Fourier transform-infrared spectra of the blue ballpoint inks exposed to ultraviolet light were studied. This research discovered that the solvents volatilized rapidest, and then the rate of polymerization and cross-link process of the epoxy resin took second place, and the decomposition of triarylmethane dyes was slower, and alkyd resin was relatively steady. It was as a new means for further distingusihing writting inks. Meanwhile, the means could determine the age of inks. The relative ratio of peak height was applied to describe the process of the change and on the basis of the curve fitting the errors coming from different strokes could be aviod. The advantages above are very important in practical examinations.

【基金】 公安部九五攻关课题
  • 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,2000年09期
  • 【被引频次】16
  • 【下载频次】154
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