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电极扩散层内物质浓度及分布研究方法进展

Development of Research Method of Concentration Observation and Distribution in Electrode Diffusion Layer

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【作者】 杨玉书夏之宁孙冠芸唐守渊

【Author】 Yang Yushu; La Zhining; Sun Guanyun; Tang Shouyuan (College of Environment and Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044)

【机构】 重庆大学环境与化学化工学院!重庆400044

【摘要】 评述了测试电极扩散层内物质浓度及分布的各种方法,分别从方法原理、实验装置、影响因素及其应用等方面加以论述,评价了各种方法的特点,并对发展方向进行了展望。共引用文献52篇。

【Abstract】 A review with 52 references is presented on varieties research methods for concentration observation and distribution in electrode diffusion layer. These methods depended on different principles, such as chemical analysis of resolving diffusion layer solution after fast freezing bulk electrolyte, absorption spectrometry and diffractive spectrometry based on the light absorbance change, interferometry and deflection spectrometry based on the refractive index change, Raman microprobe spectroscopy based on Raman spectroscopy and microelectrode probe based on electrochemical analysis. All of these methods are discussed from the aspects of principle, instrumentals, influence factors, features and application to electrochemistry. Perspective of this research direction is also discussed.

【基金】 国家自然科学基金!(No,29775035);国家教育部优秀年轻教师基金
  • 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,2000年07期
  • 【分类号】O646
  • 【被引频次】2
  • 【下载频次】129
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