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咪唑和2,5-二羟基-1,4苯醌与Fe(Ⅱ)混配配合物的合成与表征
Synthesis and Characterization of Mixed Ligand Complex of Fe (Ⅱ) with 2,5-dihydroxy-1,4-benzoquinone and Imidazole
【摘要】 在乙醇和水的混合溶剂中,用2,5-二羟基-1,4-苯醌阴离子(DHBQ)为桥配体,咪唑(IMI)为协配体,合成了Fe(Ⅱ)的混配配合物,通过元素分析,紫外光谱,红外光谱和差热──热重分析,可以确定此配合物具有链状结构,组成为[Fe(u-DHBQ)(IMI)H2O]n。
【Abstract】 A novel one-dimension linear Fe (Ⅱ) complex using the dianion of 2, 5 -dihydroxy-1, 4-benzoquinone and imidazde has been synthesized in mixed solvents of water and ethanol. It was characterized by elemental analysis, IR spectra, UV spectra and DTA-TG techniques. The composition of this complex is [Fe(u-DHBQ) (IMI) H2O]n.
【关键词】 混配配合物;
2,5-二羟基-1,4苯醌;
咪唑;
合成;
表征;
【Key words】 mixed ligand complex; 2, 5 -dihydroxy -1, 4 - benzoquinone; imidazole; synthesis; characterization.;
【Key words】 mixed ligand complex; 2, 5 -dihydroxy -1, 4 - benzoquinone; imidazole; synthesis; characterization.;
【基金】 浙江省教委研究计划项目!(19990525)
- 【文献出处】 淮北煤师院学报(自然科学版) ,JOURNAL OF HUAIBEI INDUSTRY TEACHERS COLLEGE (NATURAL SCIENCES EDITION) , 编辑部邮箱 ,2000年03期
- 【分类号】O626
- 【被引频次】1
- 【下载频次】117