节点文献
桂林市及近郊土壤汞的分布和污染研究
Soil mercury distribution and pollution in urban and suburbs of Guilin
【摘要】 通过对桂林市区及近郊表层、底层土壤汞的系统取样、测试和编图,阐明了本区土壤汞的分布规律,确定了土壤汞的污染区段和污染程度。在上述工作的基础上,结合基岩汞测量、热释汞方法和重金属元素组合分析,对土壤汞的来源、污染元素组合和汞的赋存状态进行了初步探讨。
【Abstract】 By means of the systematically sampling, analysis and mapping in urban and suburbs of Guilin, the mercury distribution in the surface and bottom soil has been clarified, meanwhile the pollution sections and the pollution level also have been determined. Based on these works, with mercury analysis of the bedrock, factor analysis of heavy metal elements and heat release mercury method, the elementary study on the mercury source and the mercury phase states and the element association of pollution have been conducted.Mercury content in soil of this area is high in west and low in east horizontally, which is consistent to the district of the west (industrial and residential area) and the east (agricultural area). The high mercury pollution has emerged in the center of the west, which has affected the crops. In profile, the mercury content is high in horizon A and low in horizon B. In horizon A, the soil mercury content ranges from 76 × 10-9 to 5 822 ×10-9, and its geometric mean value is 341×10-9. In horizon B, the content ranges from 52. 3 × 10-9 to 1 210×10-9, and its geometric mean value is 240×10-9. The mercury pollution in horizon A distributes extensively and seriously, and part of the horizon B also has been polluted in degrees. In the non-polluted area, the geometric mean value is 204 ×10-9 in horizon A and 148 × 10-9 in horizon B, which is much higher than the nature content in the other area of our country. The weathering of the enriched-mercury carbonaceous shale in YangUan Stage, Lower Carboniferous is the chief factor to the high mercury background of this area, industrial manufacture and city living are the main source of mercury pollution, and aghcultural activities make the mercury pollution spread further.The factor analysis shows that Hg and Cr, Zn, Cu, Pb, Cd are isolated factors in non-polluted ana, and in polluted area, Hg and Cu, Pb form one factor. The mercury pollution is obviously related to Cu and Pb pollution. The main phase states of mercury are microthermal mercury(Hg2Cl2, HgCl2 and some organic mercury), the secondary are absorbed mercury, sulfide mercury and mesothermal mercury. The phase states of mercury are more complicated in horizon A than in horizon B, and more complex in polluted area than in non-polluted one.
【Key words】 mercury; soil pollution; environmental geochemistry; Guangxi Zhuangzu Zizhiqu;
- 【文献出处】 地球化学 ,GEOCHIMICA , 编辑部邮箱 ,2000年01期
- 【分类号】X142
- 【被引频次】70
- 【下载频次】637