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杂多酸掺杂聚苯胺的表征及催化研究进展

Recent progress in character and catalysis of heteropolyacids doped polyaniline

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【作者】 吕仁庆马荔曹作刚龚剑瞿伦玉

【Author】 LU Ren qing 1,Ma Li 1,CAO Zuo gang 1,GONG Jian 2,QU Lun yu 2(1 Department of Chemical Engineering,University of Petroleam,Dongying 257062, China; 2 College of Chemistry,Northeast Normal University,Changchun 130024, China)

【机构】 华东石油大学炼制系!山东东营257062东北师范大学化学学院!吉林长春130024

【摘要】 近年来 ,杂多酸的催化研究备受人们的关注 .寻找适当的载体 ,将杂多酸有效地分散开 ,已成为催化应用的关键 .聚苯胺以其独特的掺杂现象和良好的稳定性 ,为杂多酸催化载体的选择提供了又一新的研究课题 .现就杂多酸掺杂聚苯胺的光谱表征及催化研究作一简要的概述

【Abstract】 Heteropolyacids and their salts have been extensively and intensively studied because of their inferesting redox as well as acid-base properties which,in turn,cause their application in heterogeneous and homogeneous catalysis. Reserach effort has been directed towards the entrapment of heteropolyanions in suitable supports,such as activated carbon,zeolite,silica,bauxite,bentonite,montmorillonite,modified clay such as k-10,ion exchange resion,transition metal mixed oxides,pillared layered double hydroxides,conjugated polymer such as polyacetylene,polypyrrole and polyaniline etc.The prepartion,characterization of heteropolyacids doped polyaniline(abbreviated PAN) and their catalytic conversion of isopropanol as the probe reaction are surveyed in this paper.

【关键词】 杂多酸聚苯胺掺杂
【Key words】 heteropoly acidpolyanilinedoping
【基金】 国家自然科学基金!资助项目 ( 2 96 710 0 4 )
  • 【文献出处】 东北师大学报(自然科学版) ,JOURNAL OF NORTHEAST NORMAL UNIVERSITY (NATURAL SCIENCE EDITION) , 编辑部邮箱 ,2000年01期
  • 【分类号】O633
  • 【被引频次】25
  • 【下载频次】594
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