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双相MlNi3.7Al0.4Cu0.4微晶贮氢合金的结构及活化性能

MICROSTRUCTURE AND ACTIVATION PROPERTIES OF DOUBLE-PHASE MINi3.7A10.4Cu0.4 HYDROGEN-STORAGE ALLOY

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【作者】 侯万良常新春王建强郝云彦张海峰尹君胡壮麒

【Author】 HOU Wanliang CHANG Xinchun; WANG Jianqiang ;HAO Yunyan ZHANG Haifeng; YIN Jun ;HU Zhuangqi (State Key Lab for RSA, Institute of Metal Research, The Chinese Academy Of Sciences, Shenyang 11001 5)

【机构】 中国科学院金属研究所快速凝固非平衡合全国家重点实验室中国科学院金属研究所快速凝固非平衡合金国家重点实验室中国科学院金属研究所快速凝固非平衡合金国家?

【摘要】 测试和分析了新型超声气体雾化双相复合 MlNi3.7A10.4Cu0.4微晶贮氢合金的微观组织结构 及电化学活化性能结果表明,这种贮氢合金的微观结构为双相复合结构,基体为AB5(A=La,Ce,Nd, Pr, B=Ni, Al, Cu)相,富稀土的 AB相在基体中呈不连续网状分布,在相界面存在淬火裂纹。电化学 活化性能优越,活化次数仅为 1~3次。

【Abstract】 Microstructure and activation properties of a new microcrystalline MINi3.7AIo.4Cuo.4 hydrogen-storage alloy prepared by gas atomization was investigated in this paper. The it was shown that there exists eutectic double-phase structure consisting of ABS base phase and AB second phase along grain boundaries. The activating property measured was in an advantageous position with only 1-3 cycles, which was attributed to the appearance of large quantities of fresh surfaces within powder particle as a result of the difference in hydrogen--absorbing ability between AB5 and AB phases.

【基金】 国家自然科学基金!59671027
  • 【文献出处】 材料研究学报 ,CHINESE JOURNAL OF MATERIAL RESEARCH , 编辑部邮箱 ,2000年S1期
  • 【分类号】TG139
  • 【被引频次】6
  • 【下载频次】39
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