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重庆电厂炉前煤及飞灰中As元素在有机酸作用下的淋滤行为
Releasing of As in Coal and Fly Ash of Chongqing Power Plant under Organic Acid Conditions
【摘要】 采用模拟酸雨手段 ,突出有机酸对 As元素的淋出作用。分别配置 p H=4.47的硝酸、乙酸及硝酸与乙酸的混酸三种淋滤液 ,对重庆电厂炉前煤及飞灰中的 As元素进行 40 h的淋滤实验 ,以探讨有机酸淋滤条件下 As元素的淋出行为。结果表明 :有机酸淋滤液对炉前煤及飞灰中的 As元素具有较强的淋出作用 ,有机酸中 H+的缓冲释放作用是导致 As元素较强淋出率的主要因素。
【Abstract】 This paper mainly discussed the leaching characteristics of As in coal and fly ash of Chongqing Power Plant through the leaching experiments by using the simulated acid rain.HNO 3,CH 3COOH and mixed acid (with pH value 4.47)leaching solutions were provided to carry out the 40h leaching experiments.The results showed that large amounts of As were leached from coal and fly ash under organic acid leaching solutions,and H + buffering of organic acid played an important role on As releasing.
- 【文献出处】 重庆环境科学 ,CHONGQING ENVIRONMENTAL SCIENCE , 编辑部邮箱 ,2000年04期
- 【分类号】X501
- 【被引频次】12
- 【下载频次】140