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MFI型分子筛膜的制备与表征

The Synthesis and Characterization of MFI Zeolite Membrane

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【作者】 张延风卢冠忠许中强陈庆龄

【Author】 ZHANG Yanfeng 1, LU Guanzhong 1, XU Zhongqiang 1,2 , CHEN Qingling 2 (1 Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology of SINOPEC, Shanghai 201208, China)

【机构】 华东理工大学工业催化研究所!上海200237中国石油化工集团公司!上海201208上海石油化工研究院

【摘要】 用原位水热合成法在α Al2 O3 陶瓷管上合成出MFI型分子筛膜 .采用超声清洗的方法表征了分子筛晶体的附着强度 ,并用XRD和SEM等手段对分子筛膜进行了表征 .渗透数据表明 ,气体透过膜时不遵从努森扩散机理 ;此分子筛膜具有分子筛分作用 ,基本无缺陷

【Abstract】 MFI zeolite membrane was prepared on α Al 2O 3 substrate tube by in situ hydrothermal synthesis. The ultrasonic cleaner was used to evaluate the adhesion strength of zeolite crystals on the substrate. The ultrasonic cleaning method, combined with XRD, SEM and other characterization techniques, is effective for characterization of zeolite membrane. The gas permeation behavior through MFI zeolite membrane is different from the Knudsen mechanism, indicating that the MFI zeolite membrane has no defects and has the ability of sieving molecules.

  • 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,2000年05期
  • 【分类号】O643
  • 【被引频次】16
  • 【下载频次】303
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