节点文献

活性炭负载钌基氨合成催化剂的制备和催化活性

Preparation and Catalytic Activity of Active Carbon-Supported Ruthenium Catalyst for Ammonia Synthesis

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 王晓南朱虹夏伟琴刘化章

【Author】 WANG Xiaonan, ZHU Hong, XIA Weiqin, LIU Huazhang(Institute of Catalysis, Zhejiang University of Technology, Hangzhou 310014, China)

【机构】 浙江工业大学催化研究所!杭州310014

【Abstract】 A series of active carbon supported ruthenium based catalysts, promoted by alkali and alkaline earth nitrate, are prepared by impregnation method and with RuCl 3·3H 2O as precursor. Effects of support, promoter and preparation conditions on catalytic activity are discussed. The catalytic activity is evaluated with a fixed bed micro reactor at lower pressure. The results show that the impregnation sequence affects the catalytic activity obviously. Ba Ru K/C is the preferred impregnation sequence. And effects of nature, producing area and pre treatment of the support on catalytic activity are also examined. Catalytic activity increases with the amount of Ru deposited on the support, it attains maximum when Ru loading is 8%. Optimal molar ratio of promoter to Ru is 10.

【关键词】 活性炭负载型催化剂氨合成
【Key words】 rutheniumactive carbonsupported catalystammonia synthesis
  • 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,2000年03期
  • 【分类号】O643
  • 【被引频次】85
  • 【下载频次】588
节点文献中: 

本文链接的文献网络图示:

本文的引文网络