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制备方法对锶改性氧化铝的高温热稳定性的影响

The Influence of Preparation Methods on the Thermal Stability of Alumina Modified by Strontium

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【作者】 刘勇陈晓银杨竹仙王敬先何阿弟

【Author】 LIU Yong, CHEN Xiaoyin, YANG Zhuxian, WANG Jingxian, HE Adi (Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China)

【机构】 复旦大学环境科学与工程系!上海200433

【Abstract】 The thermal stabilization mechanism of strontium and effect of preparation method on the thermal stability of Sr modified alumina and the stabilization effect of strontium species have been investigated by measuring the BET specific surface area and powder X ray diffraction. The results show that strontium species can stabilize the alumina at high temperature and the stabilization effect of the strontium species increases with the rise of strontium content, however, the overabundance of strontium species weakens its stabilization effect. The preparation method influences the thermal stability of alumina and stabilization effect of strontium. The thermal stability of Sr modified alumina prepared by sol gel method is superior to that of samples prepared by gelation and impregnation. At high temperature, it is probable that the dispersed strontium species instead of hexaaluminate stabilizes the alumina.

【基金】 福特-中国研究与发展基金资助项目!( 9712 3 0 3 )
  • 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,2000年03期
  • 【分类号】O642
  • 【被引频次】26
  • 【下载频次】251
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