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水杨醛甘氨酸乙酯与龙脑酯希夫碱的合成
Synthesis of Salicylaldehyde Glycine Ester Schiff Base
【摘要】 利用水杨醛与甘氨酸乙酯和手性甘氨酸(一)龙脑酯合成了较为稳定的希夫碱,由于存在分子内氢键,反应容易发生,产率均在90%以上,产物比较稳定.手性水杨酸甘氨酸(一)龙脑酯希夫碱未见文献报道.两化合物结构均经波谱分析和元素分析数据确证.
【Abstract】 Two Schiff bases were synthesized by reaction of salicylaldehyde with glycineethyl ester and glycine (-)-bornyl ester. The latter chiral Schiff base has not beenreported. They are stable and exist in solid state due to the intramolecular hydrogenbonding. Their structures were identified on the basis of analytical data andspectroscopic data.
【基金】 国家自然科学基金
- 【文献出处】 北京服装学院学报 ,JOURNAL OF BEIJING INSTITUTE OF CLOTHING , 编辑部邮箱 ,2000年01期
- 【分类号】O621.34
- 【被引频次】5
- 【下载频次】247