【摘要】 合成了一种四氮杂大环高价银配合物AgL(ClO4) 2 ,其中L为 5,1 2 -二甲基 - 7,1 4二苯基 - 1 ,4,8,1 1 -四氮杂环十四烷 (简写Ph2 Me2 [1 4]aneN4)。经元素分析、红外光谱、摩尔电导、电子顺磁共振等方法对配合物进行了表征 ,并研究了它的循环伏安性质。更多还原

【Abstract】 The silver(Ⅱ) complex of AgL(ClO 4) 2 was synthesis and characterized by elemental analysis,molar conductance,IR and ESR.The Ag(Ⅱ) ion was more lickly to be coordination by tetranitrogen macrocyclic ligand in an approximately squre-planar geometry.The cyclic voltammetric properties of AgL(ClO 4) 2 have also been investigated.更多还原