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快速凝固Ni50Al50合金加氢催化剂的研究
Study on Hydrogenation Catalysts Made by Ni50Al50 Rapidly Solidified Alloys
【摘要】 以旋铸法制备快速凝固Ni50Al50合金条带,经球磨、活化处理后制成了骨架镍催化剂.利用金相检验,XRD,BET等技术对催化剂的整体结构和表面状态进行分析,发现快凝催化剂与常规催化剂相比,具有较小的比表面积,相似的晶粒度和略大的点阵参数.对比研究了常规骨架镍催化剂和快凝骨架镍催化剂的油脂加氢性能,结果表明,在相同的化学反应条件下,快凝骨架镍的油脂加氢活性比常规催化剂的高出约0.5倍.
【Abstract】 Rapidly solidified Ni50Al50 alloy ribbons are prepared, ground and activated into RaneyNi catalyst, then they are investigated and analyzed with X-ray diffraction (XRD), BET measurements,The results indicate that the rapidly solidified Ni50Al50 catalyst has smaller surface area, similar grain size and a little bigger lattice parameter, compared with conventionally prepared Ni50Al50 catalyst.The results of the oil hydrogenation show that the activity of rapidly solidified Ni50Al50 catalyst is about half times higher than that of the conventionally prepared Ni50Al50 catalyst under the same reaction conditions.
【Key words】 rapid solidification; conventional solidification; RaneyNi catalyst; activity; grain size;
- 【文献出处】 郑州工业大学学报 ,JOURNAL OF ZHENGZHOU UNIVERSITY OF TECHNOLOGY , 编辑部邮箱 ,1999年02期
- 【分类号】TG113.12
- 【被引频次】10
- 【下载频次】73