【摘要】 以硫酸为介质，电解ＭｎＳＯ４ ，以制取Ｍｎ３＋ ，将邻氯甲苯氧化为邻氯苯甲醛．通过电解氧化正交实验和ＭｎＳＯ４ 单因素实验，得到了电解最佳条件，优化条件下电流效率达８４．３０ ％ ．通过有机氧化正交实验，并结合工艺路线，优选了最适宜氧化条件，即硫酸浓度为６ ．８ ｍｏｌ／Ｌ，温度为８０ ℃，原料配比为１：３，搅拌转速为５００ ｒ／ｍｉｎ．在此条件下，醛产率达９０ ．６３ ％ ，反应速率为６ ．１８３ ⅹ１０－ ３ ｍｏｌ·Ｌ－１·ｍｉｎ－ １ ．该工艺路线简单，具有一定的工业应用价值更多还原

【Abstract】 The oxidation of o-chlorobenzaldehyde from o-chlorotoluene is conducted using Mn 3+ in sulfuric acid as a mediator,and the Mn 3+ is generated by electrolytic oxidation of manganous sulfate.The optimum conditions of electrolytic oxidation experiment are determined through the orthogonal tests and mono-factor optimization experiments of manganous sulfate, and current efficiency is 84.30%.Reaction conditions of organic oxidation are also optimized to obtain maximum oxidation yield for o-chlorobenzaldehyde and reaction rate through the optional test.The yield for o-chlorobenzaldehyde attains 90.63%,and the reaction rate is 6.183ⅹ10 -3 mol·L -1 ·min -1 .The process can be used in actual industrial production.更多还原