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氧化物的水合物酸碱性的Z/r标度及其规律性

The Z/r Criterion and Regularity of the Acidic-Basic Property of Hydrated Oxides

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【作者】 贾汉东申小清李海霞王敏

【Author】 Jia Handong Shen Xiaoqing Li Haixia Wang Min (Chemical and Engineering College, Zhengzhou University)

【机构】 郑州大学化学化工学院!郑州450052郑州大学化学化工学院!郑州450052郑州大学化学化工学院!郑州450052河南中医学院

【摘要】 用中心离子的有效离子势Z/r来标度氧化物的水合物酸碱性,并绘出了Z/r- Z(原子序数)图.从图上可简明、直观地看出氧化物的水合物酸碱性已知的递变规律.另外还发现:Z/r 大于6.7 者为酸、小于5.0 者为碱、介于两者之间者呈两性.所得结果与事实相符.

【Abstract】 The acidic basic property of hydrated oxides was characterized by the effective static potential Z * /r of the center ions and the drawing of Z * /r -Z (atomic number) has been made. The known regularity of the acidic basic property of hydrated oxides can be seen from the drawing simply and directly. Moreover, it has also been discovered that hydrated oxides with Z * /r above 6.7 are acids, that with Z * /r below 5.0 bases, and that with Z * /r between 6.7 to 5.0 amphoteric substances. This result coincides with the fact.

  • 【文献出处】 郑州大学学报(自然科学版) ,Journal of Zhengzhuou University(Natural Science Edition) , 编辑部邮箱 ,1999年04期
  • 【分类号】O611.6
  • 【下载频次】49
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