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连香树树皮化学成分的研究

Chemical Constituents from the Bark of Cercidiphyllum japonicum

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【作者】 王静蓉段金廒周荣汉

【Author】 WANG Jinn-Rong; DUAN Jin-Ao;ZHOU Rong-Han(Department of Plant Chemotaxonomy and Resources of Chinese Medicinal Material,China Pharmaceutical University,Nanjing 210038)

【机构】 中国药科大学植化分类及中药资源学研究室!南京210038

【摘要】 从连香树(CercidiphyllumjaponicumSieb.etZucc.)树皮中分离到8个化合物。其中7个为黄酮醇,l个为酚酸类成分。经理化测定和波谱解析,分别鉴定为:5,7-二羟基-3,8,4’-三甲氧基黄酮(Ⅰ)、3,5,7-三羟基-8,4’-二甲氧基黄酮(Ⅱ)、5,7,4’-三羟基-3,8-二甲氧基黄酮(Ⅲ)、3,5,7,4’-四羟基-8-甲氧基黄酮(Ⅳ)、3,5,7,4’-四羟基黄酮(Ⅴ)、5,7-二羟基-8,4’-二甲氧基黄酮-3-O-葡萄糖甙(Ⅶ)、5,7,4’-三羟基-8-甲氧基黄酮-3-O-葡萄糖甙(Ⅷ)和没食子酸乙酯(Ⅵ)。其中化合物Ⅶ为未见报道的新化合物。除化合物Ⅴ外,其余化合物均为首次从该属植物中分得。

【Abstract】 Eight compounds were isolated from the bark of Cercidiphyllum japonicum Sieb. et Zucc. Theirstructures were identified with spectral and chemical methods as 5, 7-dihydroxy-3, 8, 4’-trimethoxyflavone(Ⅰ), 3, 5, 7-trihydroxy-8, 4’-dimethoxyflavone (Ⅱ), 5, 7, 4’-trihydroxy -3, 8-dimethoxyflavone (Ⅲ), 3, 5,7, 4’- tetrahydroxy- 8 - methoxyflavone (Ⅳ), 3, 5, 7, 4’ - tetrdhydroxyflavone (Ⅴ), 5, 7 - d ihydroxy- 8, 4’ dimethoxy- 3 - O- glucoside (Ⅶ), 5, 7, 4’ - trihydroxy-8- methoxyflavone- 3 - O-glucoside (Ⅷ). One phenol acidcompound was identified as ethyl gallate (Ⅵ). AInong them, compound Ⅶ is a new compound that has neverbeen reported. Except compound Ⅴ, all the other compounds were isolated from this genus for the first time.

【基金】 国家自然科学基金!39470063l
  • 【文献出处】 植物学报 ,ACTA BOTANICA SINICA , 编辑部邮箱 ,1999年02期
  • 【分类号】Q946
  • 【被引频次】36
  • 【下载频次】314
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