【摘要】 合成了甲酰异羟肟酸(FHA)的Fe(Ⅲ)络合物,用元素分析等方法确定其化学式为Fe(FHA)3.利用穆斯堡尔谱、磁矩测定和电子光谱等方法确定该络合物为低自旋八面体构型.研究了不同pH值下络合物的组成,报导了甲酰异羟肟酸及其铁(Ⅲ)络合物的X射线粉末衍射数据.更多还原

【Abstract】 The iron complex of formohydroxamic acid (FHA) was synthesized Its formula was confirmed to be Fe(FHA) 3 by element analysis.The results of Mssbauer spectroscopy, magnetic property measurement and electronic spectroscopy indicated that the conformation of the complex was determined as low spin octahedral coordinates The components of the complex under various pH values have been studied and its X ray powder diffraction data are reported for the first time更多还原