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煤的红外光谱研究
STUDY ON INFRARED SPECTRA OF COALS
【摘要】 利用740型傅里叶变换红外(FTIR)光谱仪系统地研究了褐煤与风化烟煤的红外光谱.结果表明:含碳量在一个较宽的范围内煤的红外光谱图相类似,从褐煤到烟煤,随着煤化作用的加强,脂肪族C—H伸缩振动峰逐渐减弱,褐煤中存在大量原生腐植酸,烟煤中则含有大量再生腐植酸,这将为判断烟煤是否风化提出又一判据.根据煤的红外光谱还可推测其所含腐植酸种类及含量.
【Abstract】 In this paper, the infrared(IR) spectra from 4 000 to 400 cm -1 for brown and bituminou coal have been systematically studied by means of 740 model FTIR spectrometer. A similar basic skeleton for coals over a wide range of carbon content is indicated by the general similarity of the spectra. Due to the strengthening of coalification, the aliphatic C H stretching absorption bands of bituminous coal is weaker than that of brown coal. The brown coal contains a large amount of primary humic acid. The bituminous coal contains a large amount of regenerative humic acid, which will offer a standard for judging whether the coal was efflorescend. Humic acid type and content can be deduced by infrared spectra of coals.
- 【文献出处】 中南工业大学学报(自然科学版) ,JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY(NATURAL SCIENCE) , 编辑部邮箱 ,1999年04期
- 【分类号】TQ533
- 【被引频次】103
- 【下载频次】1321