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一种新型Fe-Mn-Al-Cr奥氏体不锈钢的耐蚀性能
INVESTIGATION OF ELECTROCHEMICAL CORROSION BEHAVIOR OF A NEW TYPE OF Fe-Mn-Al-Cr STAINLESS STEELS
【摘要】 研究了一系列铬含量不同而锰含量都为15%的Fe-Mn-Al-Cr钢在几种典型酸、碱、盐水溶液中的耐腐蚀性能,并与锰含量为26%的Fe-Mn-Al-Cr钢和1Cr18Ni9Ti相比较,结果表明新型的Fe-Mn-Al-Cr钢在水溶液中的耐腐蚀性能比原来的Fe-Mn-Al-Cr钢的都要好,在有些溶液中的耐蚀性能比1Cr18Ni9Ti还要好.这种新型不锈钢的价格非常低,有较高的实用价值.研究还表明,对该用种而言,铬含量升高并不意味着耐蚀性能提高,铬含量增至某一值对钢的耐蚀性能反而降低,此时组织中山现铁素体.用XPS对Fe-Mn-Al-Cr钢在0.5mol/LH2SO4中的钝化膜进行了研究.
【Abstract】 A series of new type Fe-Mn-Al-Cr stainless steels, which were cheaper than the steel containing 26% Mn, were designed. Their anodic polarization curves in 0.5mol/L H2SO4, lmol/L HNO3, 1mol/L Na2SO4 and 2mol/L NaOH showed that these new materials had better corrosion resistance than the former 26% Mn steel. The increase in chromium content did not monotonously improve their corrosion resistance. When the chromium content reached to a certain value ferrite appeared and the passiyity of alloy decreased. XPS was applied to study the structure of passive film formed in 0.5mol/L H2SO4. From the tests we wold conclude that the outer layer of the film was mainly composed of metal oxides and hydrates and its inner layer was metal oxides.
【Key words】 Fe-Mn-Al-Cr steel; Stainless steel; Corrosion resistance; Aqueous solution;
- 【文献出处】 中国腐蚀与防护学报 ,JOURNAL OF CHINESE SOCIETY FOR CORROSION AND PROTECTION , 编辑部邮箱 ,1999年03期
- 【分类号】TG178
- 【被引频次】12
- 【下载频次】163